What is relative formula mass?
Relative formula mass, Mr, tells you how heavy one formula unit of a substance is compared with one twelfth of the mass of a carbon-12 atom. To find it, add up the relative atomic masses, Ar, of every atom in the formula. The Ar values come from the periodic table: H = 1, C = 12, O = 16, Cl = 35.5. Mr has no unit, because it is a ratio of two masses.
Mr is the starting point for almost every calculation in quantitative chemistry. The mass of one mole of a substance in grams is numerically equal to its Mr, so water, with Mr = 18, has a molar mass of 18 g/mol. You need Mr to convert between mass and moles, to find the percentage by mass of an element and to work out concentrations in mol/dm³. In a balanced equation, the total Mr of the reactants, counting the balancing numbers, equals that of the products, which shows that mass is conserved.
Brackets need care. In Ca(OH)₂ the 2 applies to everything inside the bracket, so there are 2 O and 2 H: Mr = 40 + 2 × (16 + 1) = 74. A hydrate such as CuSO₄·5H₂O also contains five water molecules, so its Mr = 159.5 + 5 × 18 = 249.5.
